Potassium hydroxide




























































































Potassium hydroxide is an inorganic compound with the formula KOH, and is commonly called caustic potash.


Along with sodium hydroxide (NaOH), this colorless solid is a prototypical strong base. It has many industrial and niche applications, most of which exploit its corrosive nature and its reactivity toward acids. An estimated 700,000 to 800,000 tonnes were produced in 2005. About 100 times more NaOH than KOH is produced annually. KOH is noteworthy as the precursor to most soft and liquid soaps, as well as numerous potassium-containing chemicals. It is a white, solid that is dangerously corrosive. Most commercial samples are ca. 90% pure, the remainder being water and carbonates.[10]




Contents





  • 1 Properties and structure

    • 1.1 Structure


    • 1.2 Thermal stability



  • 2 Reactions

    • 2.1 Basicity, solubility and desiccating properties


    • 2.2 As a nucleophile in organic chemistry


    • 2.3 Reactions with inorganic compounds



  • 3 Manufacture


  • 4 Uses

    • 4.1 Precursor to other potassium compounds


    • 4.2 Manufacture of soft soaps


    • 4.3 As an electrolyte


    • 4.4 Food industry


    • 4.5 Niche applications



  • 5 Safety


  • 6 See also


  • 7 References


  • 8 External links




Properties and structure


Potassium hydroxide is usually sold as translucent pellets, which become tacky in air because KOH is hygroscopic. Consequently, KOH typically contains varying amounts of water (as well as carbonates - see below). Its dissolution in water is strongly exothermic. Concentrated aqueous solutions are sometimes called potassium lyes. Even at high temperatures, solid KOH does not dehydrate readily.[11]



Structure


At higher temperatures, solid KOH crystallizes in the NaCl crystal structure. The OH group is either rapidly or randomly disordered so that the OH
group is effectively a spherical anion of radius 1.53 Å (between Cl
and F
in size). At room temperature, the OH
groups are ordered and the environment about the K+
centers is distorted, with K+
—OH
distances ranging from 2.69 to 3.15 Å, depending on the orientation of the OH group. KOH forms a series of crystalline hydrates, namely the monohydrate KOH·H
2
O
, the dihydrate KOH·2 H
2
O
and the tetrahydrate KOH·4 H
2
O
.[12]



Thermal stability


Like NaOH, KOH exhibits high thermal stability. The gaseous species is dimeric. Because of its high stability and relatively low melting point, it is often melt-cast as pellets or rods, forms that have low surface area and convenient handling properties.



Reactions



Basicity, solubility and desiccating properties


About 121 g of KOH dissolve in 100 mL water at room temperature, which contrasts with 100 g/100 mL for NaOH. Thus on a molar basis, KOH is slightly less soluble than NaOH. Lower molecular-weight alcohols such as methanol, ethanol, and propanols are also excellent solvents.They participate in an acid-base equilibria. In the case of methanol the potassium methoxide (methylate) forms:
[13]


KOH + СН3ОН ↽−⇀displaystyle ce <=>>displaystyle ce <=>> СН3ОК + Н2О

Because of its high affinity for water, KOH serves as a desiccant in the laboratory. It is often used to dry basic solvents, especially amines and pyridines.



As a nucleophile in organic chemistry


KOH, like NaOH, serves as a source of OH
, a highly nucleophilic anion that attacks polar bonds in both inorganic and organic materials. Aqueous KOH saponifies esters:


KOH + RCOOR' → RCOOK + R'OH

When R is a long chain, the product is called a potassium soap. This reaction is manifested by the "greasy" feel that KOH gives when touched — fats on the skin are rapidly converted to soap and glycerol.


Molten KOH is used to displace halides and other leaving groups. The reaction is especially useful for aromatic reagents to give the corresponding phenols.[14]



Reactions with inorganic compounds


Complementary to its reactivity toward acids, KOH attacks oxides. Thus, SiO2 is attacked by KOH to give soluble potassium silicates. KOH reacts with carbon dioxide to give bicarbonate:


KOH + CO2 → KHCO3


Manufacture


Historically, KOH was made by adding potassium carbonate to a strong solution of calcium hydroxide (slaked lime) The salt metathesis reaction results in precipitation of solid calcium carbonate, leaving potassium hydroxide in solution:


Ca(OH)2 + K2CO3 → CaCO3 + 2 KOH

Filtering off the precipitated calcium carbonate and boiling down the solution gives potassium hydroxide ("calcinated or caustic potash"). This method of producing potassium hydroxide remained dominnt until the late 19th century, when it was largely replaced by the current method of electrolysis of potassium chloride solutions.[10] The method is analogous to the manufacture of sodium hydroxide (see chloralkali process):


2 KCl + 2 H2O → 2 KOH + Cl2 + H2

Hydrogen gas forms as a byproduct on the cathode; concurrently, an anodic oxidation of the chloride ion takes place, forming chlorine gas as a byproduct. Separation of the anodic and cathodic spaces in the electrolysis cell is essential for this process.[15]



Uses


KOH and NaOH can be used interchangeably for a number of applications, although in industry, NaOH is preferred because of its lower cost.



Precursor to other potassium compounds


Many potassium salts are prepared by neutralization reactions involving KOH. The potassium salts of carbonate, cyanide, permanganate, phosphate, and various silicates are prepared by treating either the oxides or the acids with KOH.[10] The high solubility of potassium phosphate is desirable in fertilizers.



Manufacture of soft soaps


The saponification of fats with KOH is used to prepare the corresponding "potassium soaps", which are softer than the more common sodium hydroxide-derived soaps. Because of their softness and greater solubility, potassium soaps require less water to liquefy, and can thus contain more cleaning agent than liquefied sodium soaps.[16]



As an electrolyte



Potassium carbonate, formed from the hydroxide solution leaking from an alkaline battery

Potassium carbonate, formed from the hydroxide solution leaking from an alkaline battery


Aqueous potassium hydroxide is employed as the electrolyte in alkaline batteries based on nickel-cadmium, nickel-hydrogen, and manganese dioxide-zinc. Potassium hydroxide is preferred over sodium hydroxide because its solutions are more conductive.[17] The nickel–metal hydride batteries in the Toyota Prius use a mixture of potassium hydroxide and sodium hydroxide.[18]Nickel–iron batteries also use potassium hydroxide electrolyte.



Food industry


In food products, potassium hydroxide acts as a food thickener, pH control agent and food stabilizer. The FDA considers it (as a direct human food ingredient) as generally safe when combined with "good" manufacturing practice conditions of use.[19] It is known in the E number system as E525.



Niche applications


Like sodium hydroxide, potassium hydroxide attracts numerous specialized applications, virtually all of which rely on its properties as a strong chemical base with its consequent ability to degrade many materials. For example, in a process commonly referred to as "chemical cremation" or "resomation", potassium hydroxide hastens the decomposition of soft tissues, both animal and human, to leave behind only the bones and other hard tissues.[20]Entomologists wishing to study the fine structure of insect anatomy may use a 10% aqueous solution of KOH to apply this process.[21]


In chemical synthesis, the choice between the use of KOH and the use of NaOH is guided by the solubility or keeping quality of the resulting salt.


The corrosive properties of potassium hydroxide make it a useful ingredient in agents and preparations that clean and disinfect surfaces and materials that can themselves resist corrosion by KOH.[15]


KOH is also used for semiconductor chip fabrication. See also: anisotropic wet etching.


Potassium hydroxide is often the main active ingredient in chemical "cuticle removers" used in manicure treatments.


Because aggressive bases like KOH damage the cuticle of the hair shaft, potassium hydroxide is used to chemically assist the removal of hair from animal hides. The hides are soaked for several hours in a solution of KOH and water to prepare them for the unhairing stage of the tanning process. This same effect is also used to weaken human hair in preparation for shaving. Preshave products and some shave creams contain potassium hydroxide to force open the hair cuticle and to act as a hygroscopic agent to attract and force water into the hair shaft, causing further damage to the hair. In this weakened state, the hair is more easily cut by a razor blade.


Potassium hydroxide is used to identify some species of fungi. A 3–5% aqueous solution of KOH is applied to the flesh of a mushroom and the researcher notes whether or not the color of the flesh changes. Certain species of gilled mushrooms, boletes, polypores, and lichens[22] are identifiable based on this color-change reaction.[23]



Safety


Potassium hydroxide and its solutions are severe irritants to skin and other tissue.[24]



See also


  • Potash

  • Soda lime


  • Saltwater soap – sailors' soap


References




  1. ^ ab Lide, D. R., ed. (2005). CRC Handbook of Chemistry and Physics (86th ed.). Boca Raton (FL): CRC Press. p. 4-80. ISBN 0-8493-0486-5..mw-parser-output cite.citationfont-style:inherit.mw-parser-output .citation qquotes:"""""""'""'".mw-parser-output .citation .cs1-lock-free abackground:url("//upload.wikimedia.org/wikipedia/commons/thumb/6/65/Lock-green.svg/9px-Lock-green.svg.png")no-repeat;background-position:right .1em center.mw-parser-output .citation .cs1-lock-limited a,.mw-parser-output .citation .cs1-lock-registration abackground:url("//upload.wikimedia.org/wikipedia/commons/thumb/d/d6/Lock-gray-alt-2.svg/9px-Lock-gray-alt-2.svg.png")no-repeat;background-position:right .1em center.mw-parser-output .citation .cs1-lock-subscription abackground:url("//upload.wikimedia.org/wikipedia/commons/thumb/a/aa/Lock-red-alt-2.svg/9px-Lock-red-alt-2.svg.png")no-repeat;background-position:right .1em center.mw-parser-output .cs1-subscription,.mw-parser-output .cs1-registrationcolor:#555.mw-parser-output .cs1-subscription span,.mw-parser-output .cs1-registration spanborder-bottom:1px dotted;cursor:help.mw-parser-output .cs1-ws-icon abackground:url("//upload.wikimedia.org/wikipedia/commons/thumb/4/4c/Wikisource-logo.svg/12px-Wikisource-logo.svg.png")no-repeat;background-position:right .1em center.mw-parser-output code.cs1-codecolor:inherit;background:inherit;border:inherit;padding:inherit.mw-parser-output .cs1-hidden-errordisplay:none;font-size:100%.mw-parser-output .cs1-visible-errorfont-size:100%.mw-parser-output .cs1-maintdisplay:none;color:#33aa33;margin-left:0.3em.mw-parser-output .cs1-subscription,.mw-parser-output .cs1-registration,.mw-parser-output .cs1-formatfont-size:95%.mw-parser-output .cs1-kern-left,.mw-parser-output .cs1-kern-wl-leftpadding-left:0.2em.mw-parser-output .cs1-kern-right,.mw-parser-output .cs1-kern-wl-rightpadding-right:0.2em


  2. ^ abcdef "potassium hydroxide". chemister.ru. Archived from the original on 18 May 2014. Retrieved 8 May 2018.


  3. ^ "A18854 Potassium hydroxide". Alfa Aesar. Thermo Fisher Scientific. Archived from the original on 19 October 2015. Retrieved 26 October 2015.


  4. ^ Seidell, Atherton; Linke, William F. (1952). Solubilities of Inorganic and Organic Compounds. Van Nostrand. Retrieved 2014-05-29.


  5. ^ Popov, K.; et al. (2002). "7Li, 23Na, 39K and 133Cs NMR comparative equilibrium study of alkali metal cation hydroxide complexes in aqueous solutions. First numerical value for CsOH formation". Inorganic Chemistry Communications. 3 (5): 223–225. doi:10.1016/S1387-7003(02)00335-0. ISSN 1387-7003. Retrieved October 20, 2018.


  6. ^ ab Zumdahl, Steven S. (2009). Chemical Principles 6th Ed. Houghton Mifflin Company. p. A22. ISBN 978-0-618-94690-7.


  7. ^ abc Sigma-Aldrich Co., Potassium hydroxide. Retrieved on 2014-05-18.


  8. ^ abc "NIOSH Pocket Guide to Chemical Hazards #0523". National Institute for Occupational Safety and Health (NIOSH).


  9. ^ Chambers, Michael. "ChemIDplus - 1310-58-3 - KWYUFKZDYYNOTN-UHFFFAOYSA-M - Potassium hydroxide [JAN:NF] - Similar structures search, synonyms, formulas, resource links, and other chemical information". chem.sis.nlm.nih.gov. Archived from the original on 12 August 2014. Retrieved 8 May 2018.


  10. ^ abc Schultz, Heinz; Bauer, Günter; Schachl, Erich; Hagedorn, Fritz; Schmittinger, Peter (2005). "Potassium Compounds". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim, Germany: Wiley-VCH. doi:10.1002/14356007.a22_039. ISBN 978-3-527-30673-2.


  11. ^ Holleman, A. F; Wiberg, E. (2001). Inorganic Chemistry. San Diego: Academic Press. ISBN 978-0-12-352651-9.


  12. ^ Wells, A.F. (1984). Structural Inorganic Chemistry. Oxford: Clarendon Press. ISBN 978-0-19-855370-0.


  13. ^ Platonov, Andrew Y.; Kurzin, Alexander V.; Evdokimov, Andrey N. (2009). "Composition of Vapor and Liquid Phases in the Potassium Hydroxide + Methanol Reaction System at 25 °С". J. Solution Chem. 39 (3): 335–342. doi:10.1007/s10953-010-9505-1.


  14. ^ W. W. Hartman (1923). "p-Cresol". Organic Syntheses. 3: 37. doi:10.15227/orgsyn.003.0037.; Collective Volume, 1, p. 175


  15. ^ ab Römpp Chemie-Lexikon, 9th Ed. (in German)


  16. ^ K. Schumann; K. Siekmann (2005). "Soaps". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a24_247. ISBN 978-3527306732.


  17. ^ D. Berndt; D. Spahrbier (2005). "Batteries". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a03_343. ISBN 978-3527306732.


  18. ^ "Toyota Prius Hybrid 2010 Model Emergency Response Guide" (PDF). Toyota Motor Corporation. 2009. Archived from the original (PDF) on 2011-10-29.


  19. ^ "Compound Summary for CID 14797 - Potassium Hydroxide". PubChem.


  20. ^ Green, Margaret (January 1952). "A RAPID METHOD FOR CLEARING AND STAINING SPECIMENS FOR THE DEMONSTRATION OF BONE". The Ohio Journal of Science. 52 (1): 31–33. Archived from the original on 8 January 2015. Retrieved 20 November 2012.


  21. ^ Thomas Eisner (2003). For the Love of Insects. Harvard University Press. p. 71.


  22. ^ Elix, J.A.; Stocker-Wörgötter, Elfie (2008). "Chapter 7: Biochemistry and secondary metabolites". In Nash III, Thomas H. Lichen Biology (2nd ed.). New York: Cambridge University Press. pp. 118–119. ISBN 978-0-521-69216-8.


  23. ^ Testing Chemical Reactions Archived 2009-10-15 at the Wayback Machine at MushroomExpert.com


  24. ^ Potassium hydroxide, SIDS Initial Assessment Report For SIAM 13. Bern, Switzerland, 6-9 November 2001. Archived 3 January 2018 at the Wayback Machine By Dr. Thaly LAKHANISKY. Date of last Update: February 2002



External links


Potassium hydroxide

Crystal structure of KOH

Pellets of potassium hydroxide
Names

IUPAC name
Potassium hydroxide

Other names
Caustic potash, Lye, Potash lye, Potassia, Potassium hydrate, KOH

Identifiers

CAS Number



  • 1310-58-3 ☑Y


3D model (JSmol)


  • Interactive image


ChEBI


  • CHEBI:32035 ☑Y


ChemSpider


  • 14113 ☑Y


ECHA InfoCard

100.013.802

EC Number
215-181-3

E number
E525 (acidity regulators, ...)


PubChem CID


  • 14797


RTECS number
TT2100000

UNII


  • WZH3C48M4T ☑Y


UN number
1813




Properties

Chemical formula

KOH

Molar mass
56.11 g mol−1
Appearance
white solid, deliquescent

Odor
odorless

Density
2.044 g/cm3 (20 °C)[1]
2.12 g/cm3 (25 °C)[2]

Melting point
360[3] °C (680 °F; 633 K)

Boiling point
1,327 °C (2,421 °F; 1,600 K)

Solubility in water

85 g/100 g (-23.2 °C)
97 g/100 mL (0 °C)
121 g/100 mL (25 °C)
138.3 g/100 mL (50 °C)
162.9 g/100 mL (100 °C)[1][4]

Solubility
soluble in alcohol, glycerol
insoluble in ether, liquid ammonia

Solubility in methanol
55 g/100 g (28 °C)[2]

Solubility in isopropanol
~14 g / 100 g (28 °C)

Basicity (pKb)
−0.7[5](KOH(aq) = K+ + OH)


Magnetic susceptibility (χ)

−22.0·10−6 cm3/mol


Refractive index (nD)

1.409 (20 °C)
Structure

Crystal structure

rhombohedral
Thermochemistry


Heat capacity (C)

65.87 J/mol·K[2]


Std molar
entropy (So298)

79.32 J/mol·K[2][6]


Std enthalpy of
formation (ΔfHo298)

-425.8 kJ/mol[2][6]


Gibbs free energy (ΔfG˚)

-380.2 kJ/mol[2]
Hazards

Safety data sheet

ICSC 0357

GHS pictograms

The corrosion pictogram in the Globally Harmonized System of Classification and Labelling of Chemicals (GHS)The exclamation-mark pictogram in the Globally Harmonized System of Classification and Labelling of Chemicals (GHS)[7]

GHS signal word
Danger

GHS hazard statements


H302, H314[7]

GHS precautionary statements


P280, P305+351+338, P310[7]

NFPA 704



Flammability code 0: Will not burn. E.g., waterHealth code 3: Short exposure could cause serious temporary or residual injury. E.g., chlorine gasReactivity code 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g., liquid nitrogenSpecial hazard ALK: Alkaline.NFPA 704 four-colored diamond

0


3


0

ALK




Flash point
Non-flammable
Lethal dose or concentration (LD, LC):


LD50 (median dose)

273 mg/kg (oral, rat)[9]
US health exposure limits (NIOSH):


PEL (Permissible)

none[8]


REL (Recommended)

C 2 mg/m3[8]


IDLH (Immediate danger)

N.D.[8]
Related compounds

Other anions


Potassium hydrosulfide
Potassium amide

Other cations


Lithium hydroxide
Sodium hydroxide
Rubidium hydroxide
Caesium hydroxide

Related compounds


Potassium oxide

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).


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Infobox references




  • Newscientist article dn10104

  • MSDS from JTBaker

  • CDC - NIOSH Pocket Guide to Chemical Hazards










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