Does thermal radiation intensity really depend on object's surface colour?

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I am not a physicist, but I am trying to maintain the level of my intuition and basic knowledge in physics. Recently I tried to look at thermal radiation and black-body radiation.



After I looked through Wikipedia articles, my intuitive understanding was that thermal radiation and black-body radiation were the same thing in the sense that if there is no incoming radiation to reflect or absorb (lights are off), then any hot object will only emit its thermal radiation like if it was a black body. I thought that black-body radiation is associated with black bodies simply because in black bodies it is easier to observe and to study, because there is no need to separate reflected radiation from thermal radiation in the total outgoing radiation.



Is my understanding wrong? It contradicts the claims I've found in the Internet here and here that the intensity of thermal radiation depends on the object's surface colour. Unless the authors of these claims actually meant to say instead that the intensity at which radiation is absorbed depends on the surface colour, and if more radiation is absorbed, more will eventually be emitted, my intuition fails to see how this is possible.



Will cast iron kitchen stove emit less heat (at the same temperature) if it is painted white (or, rather, covered with thin reflective coating)? This is rather counter-intuitive for me.



If the intensity of thermal radiation really depends not only on the object's temperature but also on its surface colour, I will appreciate any references to where I could read more about the role of surface colour in thermal radiation, and how it works.










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  • Thermal radiation $neq$ blackbody radiation.
    – Rob Jeffries
    Aug 26 at 14:47














up vote
3
down vote

favorite












I am not a physicist, but I am trying to maintain the level of my intuition and basic knowledge in physics. Recently I tried to look at thermal radiation and black-body radiation.



After I looked through Wikipedia articles, my intuitive understanding was that thermal radiation and black-body radiation were the same thing in the sense that if there is no incoming radiation to reflect or absorb (lights are off), then any hot object will only emit its thermal radiation like if it was a black body. I thought that black-body radiation is associated with black bodies simply because in black bodies it is easier to observe and to study, because there is no need to separate reflected radiation from thermal radiation in the total outgoing radiation.



Is my understanding wrong? It contradicts the claims I've found in the Internet here and here that the intensity of thermal radiation depends on the object's surface colour. Unless the authors of these claims actually meant to say instead that the intensity at which radiation is absorbed depends on the surface colour, and if more radiation is absorbed, more will eventually be emitted, my intuition fails to see how this is possible.



Will cast iron kitchen stove emit less heat (at the same temperature) if it is painted white (or, rather, covered with thin reflective coating)? This is rather counter-intuitive for me.



If the intensity of thermal radiation really depends not only on the object's temperature but also on its surface colour, I will appreciate any references to where I could read more about the role of surface colour in thermal radiation, and how it works.










share|cite|improve this question























  • Thermal radiation $neq$ blackbody radiation.
    – Rob Jeffries
    Aug 26 at 14:47












up vote
3
down vote

favorite









up vote
3
down vote

favorite











I am not a physicist, but I am trying to maintain the level of my intuition and basic knowledge in physics. Recently I tried to look at thermal radiation and black-body radiation.



After I looked through Wikipedia articles, my intuitive understanding was that thermal radiation and black-body radiation were the same thing in the sense that if there is no incoming radiation to reflect or absorb (lights are off), then any hot object will only emit its thermal radiation like if it was a black body. I thought that black-body radiation is associated with black bodies simply because in black bodies it is easier to observe and to study, because there is no need to separate reflected radiation from thermal radiation in the total outgoing radiation.



Is my understanding wrong? It contradicts the claims I've found in the Internet here and here that the intensity of thermal radiation depends on the object's surface colour. Unless the authors of these claims actually meant to say instead that the intensity at which radiation is absorbed depends on the surface colour, and if more radiation is absorbed, more will eventually be emitted, my intuition fails to see how this is possible.



Will cast iron kitchen stove emit less heat (at the same temperature) if it is painted white (or, rather, covered with thin reflective coating)? This is rather counter-intuitive for me.



If the intensity of thermal radiation really depends not only on the object's temperature but also on its surface colour, I will appreciate any references to where I could read more about the role of surface colour in thermal radiation, and how it works.










share|cite|improve this question















I am not a physicist, but I am trying to maintain the level of my intuition and basic knowledge in physics. Recently I tried to look at thermal radiation and black-body radiation.



After I looked through Wikipedia articles, my intuitive understanding was that thermal radiation and black-body radiation were the same thing in the sense that if there is no incoming radiation to reflect or absorb (lights are off), then any hot object will only emit its thermal radiation like if it was a black body. I thought that black-body radiation is associated with black bodies simply because in black bodies it is easier to observe and to study, because there is no need to separate reflected radiation from thermal radiation in the total outgoing radiation.



Is my understanding wrong? It contradicts the claims I've found in the Internet here and here that the intensity of thermal radiation depends on the object's surface colour. Unless the authors of these claims actually meant to say instead that the intensity at which radiation is absorbed depends on the surface colour, and if more radiation is absorbed, more will eventually be emitted, my intuition fails to see how this is possible.



Will cast iron kitchen stove emit less heat (at the same temperature) if it is painted white (or, rather, covered with thin reflective coating)? This is rather counter-intuitive for me.



If the intensity of thermal radiation really depends not only on the object's temperature but also on its surface colour, I will appreciate any references to where I could read more about the role of surface colour in thermal radiation, and how it works.







thermal-radiation






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edited Aug 26 at 11:50

























asked Aug 26 at 10:38









Alexey

1164




1164











  • Thermal radiation $neq$ blackbody radiation.
    – Rob Jeffries
    Aug 26 at 14:47
















  • Thermal radiation $neq$ blackbody radiation.
    – Rob Jeffries
    Aug 26 at 14:47















Thermal radiation $neq$ blackbody radiation.
– Rob Jeffries
Aug 26 at 14:47




Thermal radiation $neq$ blackbody radiation.
– Rob Jeffries
Aug 26 at 14:47










3 Answers
3






active

oldest

votes

















up vote
3
down vote













Emissivity is equal to absorptivity at each wavelength. Intuitive argument (not a real proof): otherwise an object in an oven would heat up or cool down to a temperature different from that of the oven walls, and one could make a perpetuum mobile. Reference: Gustav Kirchhoff.



Metals are reflective in infrared and visible, and are not emitting much thermal radiation.



White paint though (and snow and textiles and most stuff) is quite black for wavelengths of around 10 micrometers and most of these things are approximately black body emitters at room temperature. And as Leslie's cube shows: a thin layer of isenglas varnish on a metal surface is enough to change the emissivity.






share|cite|improve this answer






















  • Possibly instead of "white paint" I should have said "reflective coating," this is what I meant.
    – Alexey
    Aug 26 at 11:48










  • Kirchhoff's law seems to be about thermodynamic equilibrium...
    – Alexey
    Aug 26 at 11:52











  • @Alexey A material with a reflective coating (for example emergency blankets) will emit much less. But a mirror with a glass surface (or the traditional isenglas varnish of Leslie's cube) will emit almost like a black body.
    – Pieter
    Aug 26 at 11:54











  • I meant truly reflective coating (at least in the relevant wavelengths).
    – Alexey
    Aug 26 at 11:56






  • 1




    Reference to Leslie's cube experiment is also helpful, maybe it should be included in the answer...
    – Alexey
    Aug 26 at 13:13

















up vote
3
down vote













Thermal radiation is not the same thing as blackbody radiation. Thermal radiation simply means you can characterise the emission from a system with a single temperature that also describes the distribution of particle speeds, occupation of energy levels etc.



It is a necessary, but insufficient, condition for blackbody radiation that the radiation is "thermal". Blackbody radiators must also be "thick" to their own radiation field, such that the radiation field is in complete thermodynamic equilibrium with the emitting matter. This can only be approximately true for any observed object and means that all light of all wavelengths should be absorbed by the object.



Blackbody emission is the most efficiently that radiative energy can be lost by a thermal emitter. Blackbody radiation has a colour, determined by Wien's displacement law, and hotter blackbodies have a radiation flux at their surfaces which increases as $T^4$.



If you paint an object with paint that only absorbs certain wavelengths, then by definition it is no longer a blackbody and will not radiate as efficiently as a blackbody at the same temperature.






share|cite|improve this answer





























    up vote
    0
    down vote













    Emissivity equals absorptivity because the same electronic transitions are involved. When such waves reach the interface they encounter the same (Fresnel) reflectivity at the material surface whether they come from inside or outside.






    share|cite|improve this answer




















    • What about the case of inelastic scattering (say, Raman scattering)? The incident wave has a different frequency than the reflected one.
      – coniferous_smellerULPBG-W8ZgjR
      Aug 26 at 12:51






    • 1




      @user54826 I suggest that you submit this as a new question after checking the existing ones to avoid a duplicate.
      – my2cts
      Aug 26 at 13:02










    • Yes, the same transition matrix elements, but there may also be other routes for decay, and the argument is more complicated. See for example hyperphysics.phy-astr.gsu.edu/hbase/optmod/eincoef.html and en.wikipedia.org/wiki/Einstein_coefficients for transitions in isolated atoms and molecules.
      – Pieter
      Aug 26 at 20:58











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    3 Answers
    3






    active

    oldest

    votes








    3 Answers
    3






    active

    oldest

    votes









    active

    oldest

    votes






    active

    oldest

    votes








    up vote
    3
    down vote













    Emissivity is equal to absorptivity at each wavelength. Intuitive argument (not a real proof): otherwise an object in an oven would heat up or cool down to a temperature different from that of the oven walls, and one could make a perpetuum mobile. Reference: Gustav Kirchhoff.



    Metals are reflective in infrared and visible, and are not emitting much thermal radiation.



    White paint though (and snow and textiles and most stuff) is quite black for wavelengths of around 10 micrometers and most of these things are approximately black body emitters at room temperature. And as Leslie's cube shows: a thin layer of isenglas varnish on a metal surface is enough to change the emissivity.






    share|cite|improve this answer






















    • Possibly instead of "white paint" I should have said "reflective coating," this is what I meant.
      – Alexey
      Aug 26 at 11:48










    • Kirchhoff's law seems to be about thermodynamic equilibrium...
      – Alexey
      Aug 26 at 11:52











    • @Alexey A material with a reflective coating (for example emergency blankets) will emit much less. But a mirror with a glass surface (or the traditional isenglas varnish of Leslie's cube) will emit almost like a black body.
      – Pieter
      Aug 26 at 11:54











    • I meant truly reflective coating (at least in the relevant wavelengths).
      – Alexey
      Aug 26 at 11:56






    • 1




      Reference to Leslie's cube experiment is also helpful, maybe it should be included in the answer...
      – Alexey
      Aug 26 at 13:13














    up vote
    3
    down vote













    Emissivity is equal to absorptivity at each wavelength. Intuitive argument (not a real proof): otherwise an object in an oven would heat up or cool down to a temperature different from that of the oven walls, and one could make a perpetuum mobile. Reference: Gustav Kirchhoff.



    Metals are reflective in infrared and visible, and are not emitting much thermal radiation.



    White paint though (and snow and textiles and most stuff) is quite black for wavelengths of around 10 micrometers and most of these things are approximately black body emitters at room temperature. And as Leslie's cube shows: a thin layer of isenglas varnish on a metal surface is enough to change the emissivity.






    share|cite|improve this answer






















    • Possibly instead of "white paint" I should have said "reflective coating," this is what I meant.
      – Alexey
      Aug 26 at 11:48










    • Kirchhoff's law seems to be about thermodynamic equilibrium...
      – Alexey
      Aug 26 at 11:52











    • @Alexey A material with a reflective coating (for example emergency blankets) will emit much less. But a mirror with a glass surface (or the traditional isenglas varnish of Leslie's cube) will emit almost like a black body.
      – Pieter
      Aug 26 at 11:54











    • I meant truly reflective coating (at least in the relevant wavelengths).
      – Alexey
      Aug 26 at 11:56






    • 1




      Reference to Leslie's cube experiment is also helpful, maybe it should be included in the answer...
      – Alexey
      Aug 26 at 13:13












    up vote
    3
    down vote










    up vote
    3
    down vote









    Emissivity is equal to absorptivity at each wavelength. Intuitive argument (not a real proof): otherwise an object in an oven would heat up or cool down to a temperature different from that of the oven walls, and one could make a perpetuum mobile. Reference: Gustav Kirchhoff.



    Metals are reflective in infrared and visible, and are not emitting much thermal radiation.



    White paint though (and snow and textiles and most stuff) is quite black for wavelengths of around 10 micrometers and most of these things are approximately black body emitters at room temperature. And as Leslie's cube shows: a thin layer of isenglas varnish on a metal surface is enough to change the emissivity.






    share|cite|improve this answer














    Emissivity is equal to absorptivity at each wavelength. Intuitive argument (not a real proof): otherwise an object in an oven would heat up or cool down to a temperature different from that of the oven walls, and one could make a perpetuum mobile. Reference: Gustav Kirchhoff.



    Metals are reflective in infrared and visible, and are not emitting much thermal radiation.



    White paint though (and snow and textiles and most stuff) is quite black for wavelengths of around 10 micrometers and most of these things are approximately black body emitters at room temperature. And as Leslie's cube shows: a thin layer of isenglas varnish on a metal surface is enough to change the emissivity.







    share|cite|improve this answer














    share|cite|improve this answer



    share|cite|improve this answer








    edited Aug 26 at 14:19

























    answered Aug 26 at 11:35









    Pieter

    5,78631026




    5,78631026











    • Possibly instead of "white paint" I should have said "reflective coating," this is what I meant.
      – Alexey
      Aug 26 at 11:48










    • Kirchhoff's law seems to be about thermodynamic equilibrium...
      – Alexey
      Aug 26 at 11:52











    • @Alexey A material with a reflective coating (for example emergency blankets) will emit much less. But a mirror with a glass surface (or the traditional isenglas varnish of Leslie's cube) will emit almost like a black body.
      – Pieter
      Aug 26 at 11:54











    • I meant truly reflective coating (at least in the relevant wavelengths).
      – Alexey
      Aug 26 at 11:56






    • 1




      Reference to Leslie's cube experiment is also helpful, maybe it should be included in the answer...
      – Alexey
      Aug 26 at 13:13
















    • Possibly instead of "white paint" I should have said "reflective coating," this is what I meant.
      – Alexey
      Aug 26 at 11:48










    • Kirchhoff's law seems to be about thermodynamic equilibrium...
      – Alexey
      Aug 26 at 11:52











    • @Alexey A material with a reflective coating (for example emergency blankets) will emit much less. But a mirror with a glass surface (or the traditional isenglas varnish of Leslie's cube) will emit almost like a black body.
      – Pieter
      Aug 26 at 11:54











    • I meant truly reflective coating (at least in the relevant wavelengths).
      – Alexey
      Aug 26 at 11:56






    • 1




      Reference to Leslie's cube experiment is also helpful, maybe it should be included in the answer...
      – Alexey
      Aug 26 at 13:13















    Possibly instead of "white paint" I should have said "reflective coating," this is what I meant.
    – Alexey
    Aug 26 at 11:48




    Possibly instead of "white paint" I should have said "reflective coating," this is what I meant.
    – Alexey
    Aug 26 at 11:48












    Kirchhoff's law seems to be about thermodynamic equilibrium...
    – Alexey
    Aug 26 at 11:52





    Kirchhoff's law seems to be about thermodynamic equilibrium...
    – Alexey
    Aug 26 at 11:52













    @Alexey A material with a reflective coating (for example emergency blankets) will emit much less. But a mirror with a glass surface (or the traditional isenglas varnish of Leslie's cube) will emit almost like a black body.
    – Pieter
    Aug 26 at 11:54





    @Alexey A material with a reflective coating (for example emergency blankets) will emit much less. But a mirror with a glass surface (or the traditional isenglas varnish of Leslie's cube) will emit almost like a black body.
    – Pieter
    Aug 26 at 11:54













    I meant truly reflective coating (at least in the relevant wavelengths).
    – Alexey
    Aug 26 at 11:56




    I meant truly reflective coating (at least in the relevant wavelengths).
    – Alexey
    Aug 26 at 11:56




    1




    1




    Reference to Leslie's cube experiment is also helpful, maybe it should be included in the answer...
    – Alexey
    Aug 26 at 13:13




    Reference to Leslie's cube experiment is also helpful, maybe it should be included in the answer...
    – Alexey
    Aug 26 at 13:13










    up vote
    3
    down vote













    Thermal radiation is not the same thing as blackbody radiation. Thermal radiation simply means you can characterise the emission from a system with a single temperature that also describes the distribution of particle speeds, occupation of energy levels etc.



    It is a necessary, but insufficient, condition for blackbody radiation that the radiation is "thermal". Blackbody radiators must also be "thick" to their own radiation field, such that the radiation field is in complete thermodynamic equilibrium with the emitting matter. This can only be approximately true for any observed object and means that all light of all wavelengths should be absorbed by the object.



    Blackbody emission is the most efficiently that radiative energy can be lost by a thermal emitter. Blackbody radiation has a colour, determined by Wien's displacement law, and hotter blackbodies have a radiation flux at their surfaces which increases as $T^4$.



    If you paint an object with paint that only absorbs certain wavelengths, then by definition it is no longer a blackbody and will not radiate as efficiently as a blackbody at the same temperature.






    share|cite|improve this answer


























      up vote
      3
      down vote













      Thermal radiation is not the same thing as blackbody radiation. Thermal radiation simply means you can characterise the emission from a system with a single temperature that also describes the distribution of particle speeds, occupation of energy levels etc.



      It is a necessary, but insufficient, condition for blackbody radiation that the radiation is "thermal". Blackbody radiators must also be "thick" to their own radiation field, such that the radiation field is in complete thermodynamic equilibrium with the emitting matter. This can only be approximately true for any observed object and means that all light of all wavelengths should be absorbed by the object.



      Blackbody emission is the most efficiently that radiative energy can be lost by a thermal emitter. Blackbody radiation has a colour, determined by Wien's displacement law, and hotter blackbodies have a radiation flux at their surfaces which increases as $T^4$.



      If you paint an object with paint that only absorbs certain wavelengths, then by definition it is no longer a blackbody and will not radiate as efficiently as a blackbody at the same temperature.






      share|cite|improve this answer
























        up vote
        3
        down vote










        up vote
        3
        down vote









        Thermal radiation is not the same thing as blackbody radiation. Thermal radiation simply means you can characterise the emission from a system with a single temperature that also describes the distribution of particle speeds, occupation of energy levels etc.



        It is a necessary, but insufficient, condition for blackbody radiation that the radiation is "thermal". Blackbody radiators must also be "thick" to their own radiation field, such that the radiation field is in complete thermodynamic equilibrium with the emitting matter. This can only be approximately true for any observed object and means that all light of all wavelengths should be absorbed by the object.



        Blackbody emission is the most efficiently that radiative energy can be lost by a thermal emitter. Blackbody radiation has a colour, determined by Wien's displacement law, and hotter blackbodies have a radiation flux at their surfaces which increases as $T^4$.



        If you paint an object with paint that only absorbs certain wavelengths, then by definition it is no longer a blackbody and will not radiate as efficiently as a blackbody at the same temperature.






        share|cite|improve this answer














        Thermal radiation is not the same thing as blackbody radiation. Thermal radiation simply means you can characterise the emission from a system with a single temperature that also describes the distribution of particle speeds, occupation of energy levels etc.



        It is a necessary, but insufficient, condition for blackbody radiation that the radiation is "thermal". Blackbody radiators must also be "thick" to their own radiation field, such that the radiation field is in complete thermodynamic equilibrium with the emitting matter. This can only be approximately true for any observed object and means that all light of all wavelengths should be absorbed by the object.



        Blackbody emission is the most efficiently that radiative energy can be lost by a thermal emitter. Blackbody radiation has a colour, determined by Wien's displacement law, and hotter blackbodies have a radiation flux at their surfaces which increases as $T^4$.



        If you paint an object with paint that only absorbs certain wavelengths, then by definition it is no longer a blackbody and will not radiate as efficiently as a blackbody at the same temperature.







        share|cite|improve this answer














        share|cite|improve this answer



        share|cite|improve this answer








        edited Aug 26 at 16:49

























        answered Aug 26 at 14:58









        Rob Jeffries

        65.7k7130223




        65.7k7130223




















            up vote
            0
            down vote













            Emissivity equals absorptivity because the same electronic transitions are involved. When such waves reach the interface they encounter the same (Fresnel) reflectivity at the material surface whether they come from inside or outside.






            share|cite|improve this answer




















            • What about the case of inelastic scattering (say, Raman scattering)? The incident wave has a different frequency than the reflected one.
              – coniferous_smellerULPBG-W8ZgjR
              Aug 26 at 12:51






            • 1




              @user54826 I suggest that you submit this as a new question after checking the existing ones to avoid a duplicate.
              – my2cts
              Aug 26 at 13:02










            • Yes, the same transition matrix elements, but there may also be other routes for decay, and the argument is more complicated. See for example hyperphysics.phy-astr.gsu.edu/hbase/optmod/eincoef.html and en.wikipedia.org/wiki/Einstein_coefficients for transitions in isolated atoms and molecules.
              – Pieter
              Aug 26 at 20:58















            up vote
            0
            down vote













            Emissivity equals absorptivity because the same electronic transitions are involved. When such waves reach the interface they encounter the same (Fresnel) reflectivity at the material surface whether they come from inside or outside.






            share|cite|improve this answer




















            • What about the case of inelastic scattering (say, Raman scattering)? The incident wave has a different frequency than the reflected one.
              – coniferous_smellerULPBG-W8ZgjR
              Aug 26 at 12:51






            • 1




              @user54826 I suggest that you submit this as a new question after checking the existing ones to avoid a duplicate.
              – my2cts
              Aug 26 at 13:02










            • Yes, the same transition matrix elements, but there may also be other routes for decay, and the argument is more complicated. See for example hyperphysics.phy-astr.gsu.edu/hbase/optmod/eincoef.html and en.wikipedia.org/wiki/Einstein_coefficients for transitions in isolated atoms and molecules.
              – Pieter
              Aug 26 at 20:58













            up vote
            0
            down vote










            up vote
            0
            down vote









            Emissivity equals absorptivity because the same electronic transitions are involved. When such waves reach the interface they encounter the same (Fresnel) reflectivity at the material surface whether they come from inside or outside.






            share|cite|improve this answer












            Emissivity equals absorptivity because the same electronic transitions are involved. When such waves reach the interface they encounter the same (Fresnel) reflectivity at the material surface whether they come from inside or outside.







            share|cite|improve this answer












            share|cite|improve this answer



            share|cite|improve this answer










            answered Aug 26 at 12:34









            my2cts

            3,4262416




            3,4262416











            • What about the case of inelastic scattering (say, Raman scattering)? The incident wave has a different frequency than the reflected one.
              – coniferous_smellerULPBG-W8ZgjR
              Aug 26 at 12:51






            • 1




              @user54826 I suggest that you submit this as a new question after checking the existing ones to avoid a duplicate.
              – my2cts
              Aug 26 at 13:02










            • Yes, the same transition matrix elements, but there may also be other routes for decay, and the argument is more complicated. See for example hyperphysics.phy-astr.gsu.edu/hbase/optmod/eincoef.html and en.wikipedia.org/wiki/Einstein_coefficients for transitions in isolated atoms and molecules.
              – Pieter
              Aug 26 at 20:58

















            • What about the case of inelastic scattering (say, Raman scattering)? The incident wave has a different frequency than the reflected one.
              – coniferous_smellerULPBG-W8ZgjR
              Aug 26 at 12:51






            • 1




              @user54826 I suggest that you submit this as a new question after checking the existing ones to avoid a duplicate.
              – my2cts
              Aug 26 at 13:02










            • Yes, the same transition matrix elements, but there may also be other routes for decay, and the argument is more complicated. See for example hyperphysics.phy-astr.gsu.edu/hbase/optmod/eincoef.html and en.wikipedia.org/wiki/Einstein_coefficients for transitions in isolated atoms and molecules.
              – Pieter
              Aug 26 at 20:58
















            What about the case of inelastic scattering (say, Raman scattering)? The incident wave has a different frequency than the reflected one.
            – coniferous_smellerULPBG-W8ZgjR
            Aug 26 at 12:51




            What about the case of inelastic scattering (say, Raman scattering)? The incident wave has a different frequency than the reflected one.
            – coniferous_smellerULPBG-W8ZgjR
            Aug 26 at 12:51




            1




            1




            @user54826 I suggest that you submit this as a new question after checking the existing ones to avoid a duplicate.
            – my2cts
            Aug 26 at 13:02




            @user54826 I suggest that you submit this as a new question after checking the existing ones to avoid a duplicate.
            – my2cts
            Aug 26 at 13:02












            Yes, the same transition matrix elements, but there may also be other routes for decay, and the argument is more complicated. See for example hyperphysics.phy-astr.gsu.edu/hbase/optmod/eincoef.html and en.wikipedia.org/wiki/Einstein_coefficients for transitions in isolated atoms and molecules.
            – Pieter
            Aug 26 at 20:58





            Yes, the same transition matrix elements, but there may also be other routes for decay, and the argument is more complicated. See for example hyperphysics.phy-astr.gsu.edu/hbase/optmod/eincoef.html and en.wikipedia.org/wiki/Einstein_coefficients for transitions in isolated atoms and molecules.
            – Pieter
            Aug 26 at 20:58


















             

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